Revised structure of deacetyl-1,10-didehydrosalvinorin G.
Tetrahedron Letters July 30, 2007 DOI: 10.1016/j.tetlet.2007.05.179 (opens in new tab)
Study at a glance
AI-extracted from the abstract| Characteristics | Peer reviewed |
|---|---|
| Topics | Salvia divinorum |
| Key points | The previously published structure of deacetyl-1,10-didehydrosalvinorin G is revised to its 8-epimer, based on NMR comparisons with salvinorin A and its 8-epimer; NOESY and chemical synthesis confirm the stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G. |
Abstract
In comparison with the NMR data of salvinorin A and its 8-epimer, the published structure of deacetyl-1,10-didehydrosalvinorin G was revised to its 8-epimer. The stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G was further confirmed by NOESY and chemical synthesis.
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- Novel neoclerodane diterpene derivatives from the smoke of salvinorin A. Tetrahedron Letters September 29, 2010
- Natural products from the hallucinogenic sage. Science progress 2010
- Highly Oxygenated Diterpenoids Associated to the Central Nervous System: Syntheses of Salvinorin and Forskolin Journal of Synthetic Organic Chemistry Japan 2009
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- Salvinorin A: the "magic mint" hallucinogen finds a molecular target in the kappa opioid receptor. TIPS - Trends in Pharmacological Sciences March 1, 2003
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