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Novel neoclerodane diterpene derivatives from the smoke of salvinorin A.

Zhongze Ma, Gang Deng, David Y W Lee

Tetrahedron Letters September 29, 2010 DOI: 10.1016/j.tetlet.2010.07.144 (opens in new tab)

Study at a glance

AI-extracted from the abstract
Characteristics Laboratory study Peer reviewed
Intervention smoking salvinorin A
Topics Salvia divinorum
Keywords Hallucinogen Psychoactive substance Combustion chemistry Pyrolysis Smoke chemistry Thermal degradation Chemical transformations Structural changes Epimerizations Rearrangements Novel compounds Neoclerodane diterpenes Diterpene derivatives New compounds Combustion products
Citations 11
Key points Eight neoclerodane diterpene derivatives were isolated from the smoke of salvinorin A, with structural changes including epimerizations, eliminations, and rearrangements.

Abstract

Salvinorin A is a naturally-occurring potent and selective kappa opioid receptor agonist, and smoking salvinorin A produces the most intense hallucinogenic effects in human. Eight neoclerodane diterpene derivatives were isolated from the smoke of salvinorin A, and their structures were identified by spectroscopic methods. The major structural changes include epimerizations, eliminations, and rearrangements.

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