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Sarah J Hill

3 papers in the library · publishing 2020-2023

Papers

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A Route to Potent, Selective, and Biased Salvinorin Chemical Space.

ACS Central Science August 23, 2023 Sarah J Hill, Nathan Dao, Vuong Q. Dang et al.

The salvinorins serve as templates for next generation analgesics, antipruritics, and dissociative hallucinogens via selective and potent agonism of the kappa-opioid receptor (KOR). In contrast to most opioids, the salvinorins lack basic amines and bind with high affinity and selectivity via complex polyoxygenated scaffolds that have frustrated deep-seated modification by synthesis. Here we...

Chemical syntheses of the salvinorin chemotype of KOR agonist.

Natural Product Reports November 18, 2020 Sarah J Hill, Aurélien U C M Brion, Ryan A Shenvi

Covering: 2000 to 2020 The hallucinogenic diterpene salvinorin A potently and selectively agonizes the human kappa-opioid receptor (KOR). Its unique attributes-lack of a basic nitrogen, rapid brain penetrance, short half-life-combined with the potential of KOR as an emerging target for analgesics have stimulated extensive medicinal chemistry based on semi-synthesis from extracts of Salvia...

A route to potent, selective and biased salvinorin chemical space

Sarah J Hill, Nathan Dao, Vuong Q. Dang et al.

The salvinorins serve as templates for next generation analgesics, antipruritics and dissociative hallucinogens via selective and potent agonism of the kappa-opioid receptor (KOR). In contrast to most opioids, the salvinorins lack basic amines and bind with high affinity and selectivity via complex polyoxygenated scaffolds that have frustrated deep-seated modification by synthesis. Here we...