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A versatile synthesis of 1-aryl-2-nitro-3-(3,4,5-trimethoxyphenyl)propenes as precursors of novel mescaline derivatives.

Daniel Dauzonne, René Royer

Chemical and Pharmaceutical Bulletin 1986 DOI: 10.1248/cpb.34.1628 (opens in new tab)

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AI-extracted from the abstract
Characteristics Synthetic chemistry paper Peer reviewed
Topics Mescaline
Keywords Tryptamine Nitro Aryl Benzene Propane Organic chemistry Molecule Stereochemistry Chemical reaction mechanisms
Citations 7
Key points A one-step reaction produces 1-aryl-2-nitro-3-(3,4,5-trimethoxyphenyl)propenes that can be reduced to new mescaline derivatives, exemplified by a compound merging mescaline and tryptamine structures.

Abstract

A convenient one-step procedure to synthesize the title compounds (3a-v) by the reaction between 1, 2, 3-trimethoxy-5-(2-nitroethyl)benzene (1) and aromatic or heterocyclic aldehydes is reported. The obtained 1-aryl-2-nitro-3-(3, 4, 5-trimethoxyphenyl)propenes can easily be reduced to provide new mescaline derivatives. As an example, 1-(3-indolyl)-2-amino-3-(3, 4, 5-trimethoxyphenyl)propane (4), which contains in the same molecule the structural features of both mescaline and tryptamine, has been prepared.

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